Novel Lithium-Containing Honeycomb Structures

作者：Kumar Vinod; Bhardwaj Neha; Tomar Nobel; Thakral Vaishali; Uma S^*

来源：Inorganic Chemistry, 2012, 51(20): 10471-10473.

DOI：10.1021/ic301125n

Rock-salt-based honeycomb structures containing Te-VI and Sb-V with innumerable prospects of properties and applications were realized in the two new series of mixed-metal oxides of lithium, Li8M2Te2O12 (M-II = Co, Ni, Cu, Zn) and Li8M2Sb2O12 (M-III = Cr, Fe, Al, Ga). The structures of Li8Co2Te2O12 and Li8Cu2Te2O12 were determined by single-crystal X-ray diffraction for the first time, and mixed-occupancy Li/M was identified.

• 出版日期2012-10-15