Memory and Development of Textures of Polydomain Nematic Elastomers

作者：Higaki Haruko; Urayama Kenji^*; Takigawa Toshikazu

来源：Macromolecular Chemistry and Physics, 2012, 213(18): 1907-1912.

DOI：10.1002/macp.201200239

• elastomers
• liquid crystal elastomers
• liquid crystalline polymers
• mechanical properties

The texture development during the polydomain-to-monodomain (PM) transition in nematic elastomers with isotropic (I-PNE) or nematic genesis (N-PNE) is studied. I-PNE exhibits a uniform polydomain texture, and the PM transition occurs at a constant small force, resulting in a uniform monodomain texture. N-PNE exhibits the Schlieren texture that is composed of large domains with many defects and is similar to that before cross-linking. N-PNE requires much more mechanical work than I-PNE for the PM transition. In N-PNE, remnants of the initial texture are still observed in the stretched aligned state, while the initial texture and dimensions are completely restored when the imposed strain is removed. The permanent memory of the initial texture becomes a robust constraint to the rotation of the local directors.

• 出版日期2012-9-26