Diaqua-1 kappa O,3 kappa O-di-mu-cyanido-1 : 2 kappa N-2 : C;2 : 3 kappa C-2 : N-dicyanido-2 kappa C-2-bis{4,4 '-dibromo-2,2 '-[propane-1,2-diyl-bis(nitrilomethylidine)]diphenolato}-1 kappa O-4,N,N ',O ';3 kappa O-4,N,N ',O '-1,3-di-iron(III)-2-nickel(II) (Retracted article. See vol. 67, pg. E16, 2011)

作者：Zhang Xiutang; Wei Peihai^*; Li Bin

来源：Acta Crystallographica Section E-Structure Reports Online, 2008, 64: M926-U622.

DOI：10.1107/S1600536808017893

The title compound, [Fe2Ni(C17H14Br2N2O2)(2)(CN)(4)(H2O)(2)] or [{Fe(C17H14Br2N2O2)(H2O)}(2)(mu-CN)(2){Ni(CN)(2)}], is iso-structural with its Mn-III-containing analogue. Each Fe-III atom is chelated by a Schiff base ligand via two N and two O atoms and is additionally coordinated by a water molecule, forming a slightly distorted octahedral geometry. The two Fe-III centres are bridged by a square-planar Ni(CN)(4) unit, which lies on an inversion centre. A two-dimensional network is formed via O-H center dot center dot center dot O and O-H center dot center dot center dot N hydrogen bonds.

• 出版日期2008-7
• 单位齐鲁师范学院