Optimized 4-V Spinel Cathode Material with High Energy Density for Li-Ion Cells Operating at 60 degrees C

作者：Lee Sanghan; Jeong Minseul; Cho Jaephil^*

来源：Advanced Energy Materials, 2013, 3(12): 1623-1629.

DOI：10.1002/aenm.201300510

• lithium-ion batteries
• cathodes
• electrode materials
• solid solutions
• electrochemistry
• lithium manganese oxide

Spinel cathodes comprising 16-m, AlPO4-coated Li1.09Mn1.83Al0.08O4 with a high energy density of 1.2 W h cm(-3) are synthesized via a conventional solid-state reaction using MnO2 and Li2CO3 at 770 degrees C for 10 h and using a solution-based coating method in bulk scale (>20 kg). The cathodes are coated by aluminum phosphate at a thickness of <10 nm. The coated cathodes exhibit a first discharge capacity of 108 mAh g(-1) and a coulombic efficiency of >99.8%, and their capacity retention is 78% after 200 cycles at a 0.5C rate in a Li-ion cell under 60 degrees C. More importantly, a Li-ion cell containing the coated cathode does not exhibit a swelling problem after 200 cycles at 60 degrees C. Transmission and scanning electron microscopy suggest that the uniformly distributed AlPO4 coating and the possible formation of a solid solution phase along the surface play key roles in enhancing the electrochemical performance of the LiMn2O4 spinel at 60 degrees C.

• 出版日期2013-12