Aminophosphine Palladium(0) Complex Supported on ZrO2 Nanoparticles (ZrO2@AEPH(2)-PPh2-Pd(0)) as an Efficient Heterogeneous Catalyst for Suzuki-Miyaura and Heck-Mizoroki Reactions in Green Media

Razavi Nasrin; Akhlaghinia Batool; Jahanshahi Roya

doi:10.1007/s10562-016-1944-x

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Aminophosphine Palladium(0) Complex Supported on ZrO2 Nanoparticles (ZrO2@AEPH(2)-PPh2-Pd(0)) as an Efficient Heterogeneous Catalyst for Suzuki-Miyaura and Heck-Mizoroki Reactions in Green Media

作者：Razavi Nasrin; Akhlaghinia Batool; Jahanshahi Roya

来源：Catalysis Letters, 2017, 147(2): 360-373.

DOI：10.1007/s10562-016-1944-x

摘要

A new aminophosphine palladium(0) complex supported on ZrO2 nanoparticles (ZrO2@AEPH(2)-PPh2-Pd(0)) was successfully synthesized and characterized using FT-IR, XRD, XPS, SEM, TEM, EDS, TGA and ICP techniques. Characterization results revealed that the synthesized catalyst had tetragonal and monoclinic structure with spherical morphology. The prepared nanocatalyst was showed excellent reactivity in the Suzuki-Miyaura and Heck-Mizoroki cross-coupling reactions. Moreover, this nanocatalyst can be easily recovered and reused for at least six cycles without deterioration in catalytic activity. [GRAPHICS] .