Preparation, characterization and magnetic properties of PANI/La-substituted LiNi ferrite nanocomposites

作者：Jiang Jing; Li Liang-Chao^*; Xu Feng

来源：Chinese Journal of Chemistry, 2006, 24(12): 1804-1809.

DOI：10.1002/cjoc.200690338

• nanocomposite
• polyaniline
• ferrite
• magnetic property

Magnetic nanocomposites containing polyaniline (PANI)-coated La-substituted LiNi ferrite (LiNi0.5La0.02Fe1.98O4) were synthesized by in situ polymerization in aqueous solution of hydrochloric acid. The nanocomposites exhibited the magnetic hysteresis nature under applied magnetic field. The saturation magnetization (M-s) and coercivity (H-c) varied with the ferrite content. The obtained nanocomposites were characterized by X-ray diffraction (XRD), transmission electron microscopy (TEM), scanning electron microscopy (SEM), Fourier transform infrared spectroscopy (FT-IR), UV-Visible spectroscopy and vibrating sample magnetometer (VSM). TEM and SEM studies showed that the nanocomposites present the core-shell structure. The results of XRD patterns, FT-IR and UV-Visible spectra indicated the formation of PANI-LiNi0.5La0.02Fe1.98O4 nanocomposites and showed that the interaction existed between PANI backbone and ferrite particles in the nanocomposites. The bonding mechanism in the nanocomposites has been proposed.

• 出版日期2006-12
• 单位浙江师范大学