An efficient, scalable synthesis of ferrocenylphosphine and dichloroferrocenylphosphine

作者：Surgenor Brian A; Taylor Laurence J; Nordheider Andreas; Slawin Alexandra M Z; Arachchige Kasun S Athukorala; Woollins J Derek; Kilian Petr^*

来源：RSC Advances, 2016, 6(7): 5973-5976.

DOI：10.1039/c5ra27594f

A new synthetic route to FcPH(2) and FcPCl(2) (Fc = ferrocenyl) is presented. This method avoids the challenging monolithiation of ferrocene, as well as any tedious purification steps. All reactions are high yielding and easily conducted on a relatively large scale, using economical and commercially available synthetic precursors.

• 出版日期2016