Post metalation of solvothermally grown electroactive porphyrin metal-organic framework thin films

作者:Kung Chung Wei; Chang Ting Hsiang; Chou Li Yao; Hupp Joseph T; Farha Omar K; Ho Kuo Chuan*
来源:Chemical communications, 2015, 51(12): 2414-2417.
DOI:10.1039/c4cc09272d

摘要

Uniform thin films of a metal-organic framework, which is constructed from free-base porphyrin linkers and hexa-zirconium nodes (MOF-525), are solvothermally grown on conducting substrates. Subsequently, solvothermal post metalations are employed to prepare the Zn-MOF-525 and Co-MOF-525 thin films. All the thin films are electroactive in aqueous media.