Stepwise self-assembly of a discrete molecular honeycomb using a multitopic metallo-organic ligand

作者：Wu, Tun; Yuan, Jie; Song, Bo; Chen, Yu-Sheng; Chen, Mingzhao; Xue, Xiaobo; Liu, Qianqian; Wang, Jun; Chan, Yi-Tsu; Wang, Pingshan^*

来源：Chemical communications, 2017, 53(50): 6732-6735.

DOI：10.1039/c7cc03715e

• RING-IN-RING
• TERPYRIDINE LIGANDS
• SUPRAMOLECULAR CHEMISTRY
• METAL CENTERS
• ARCHITECTURES
• COMPLEXES
• GIANT
• 2D
• MACROMOLECULES
• CUBOCTAHEDRON

Self-assembly of a metallo-organic ligand, composed of an inner uncomplexed 120 degrees-bis(terpyridine) and an outer extended free 120 degrees-bis(terpyridine) linked by a triple <-tpy-Ru2+-tpy-> connector, and complexed with Zn2+, gave rise to a discrete planar supra-molecular honeycomb patterned fractal. The central metallo-hexagon was surrounded by six identical metallo-hexagons which perfectly mimicked the natural simple honeycomb structure.

• 出版日期2017-6-25
• 单位中南大学