A Monolithically Integrated Gallium Nitride Nanowire/Silicon Solar Cell Photocathode for Selective Carbon Dioxide Reduction to Methane

作者：Wang Yichen; Fan Shizhao; AlOtaibi Bandar; Wang Yongjie; Li Lu; Mi Zetian^*

来源：Chemistry - A European Journal, 2016, 22(26): 8809-8813.

DOI：10.1002/chem.201601642

• carbon dioxide reduction
• gallium nitride
• photocathodes
• photoelectrocatalysis
• solar fuel

A gallium nitride nanowire/silicon solar cell photocathode for the photoreduction of carbon dioxide (CO2) is demonstrated. Such a monolithically integrated nanowire/solar cell photocathode offers several unique advantages, including the absorption of a large part of the solar spectrum and highly efficient carrier extraction. With the incorporation of copper as the co-catalyst, the devices exhibit a Faradaic efficiency of about 19% for the 8e(-) photoreduction to CH4 at -1.4 V vs Ag/AgCl, a value that is more than thirty times higher than that for the 2e(-) reduced CO (ca. 0.6%).

• 出版日期2016-6-20