Determination of Abraham model solute descriptors for three dichloronitrobenzenes from measured solubilities in organic solvents

作者：Brumfield Michela; Wadawadigi Akash; Kuprasertkul Napasorn; Mehta Sumedha; Stephens Timothy W; Barrera Maribel; De La Rosa Jennifer; Kennemer Logan; Meza Jocelin; Acree William E Jr^*; Abraham Michael H

来源：Physics and Chemistry of Liquids, 2015, 53(2): 163-173.

DOI：10.1080/00319104.2014.972555

• organic solvents
• Abraham model
• solute descriptors
• solubility
• dichloronitrobenzenes

Mole fraction solubilities are reported for 1,4-dichloro-2-nitrobenzene dissolved in 24 organic solvents of varying polarity and hydrogen-bonding character. The experimental data are used to calculate Abraham solute descriptors. The calculated solute descriptors describe the experimental data to within an overall average standard deviation of 0.081 log units. Also reported in the manuscript are Abraham model solute descriptors for both 3,4-dichloro-1-nitrobenzene and 2,3-dichloro-1-nitrobenzene based on published literature data.

• 出版日期2015-3-4