A semiconducting metal-chalcogenide-organic framework with square-planar tetra-coordinated sulfur

作者：Yang, Huajun; Luo, Min; Wu, Zhou; Wang, Wei; Xue, Chaozhuang; Wu, Tao^*

来源：Chemical communications, 2018, 54(80): 11272-11275.

DOI：10.1039/c8cc06997b

• HYDROGEN STORAGE
• ROOM-TEMPERATURE
• BUILDING UNITS
• SURFACE-AREA
• QUANTUM DOTS
• GAS SORPTION
• CHEMISTRY
• CONDUCTIVITY
• METATHESIS
• STABILITY

We demonstrated here a novel semiconducting metal-chalcogenide-organic framework (MCOF-89) with an optical bandgap through the unlikely assembly between a metal chalcogenide unit and carboxylic acid. The elusive metal-chalcogenide unit [Mn-4(mu(4)-S)] with square-planar tetra-coordinated sulfur (sptS) is for the first time observed in MOFs.

• 出版日期2018-10-14
• 单位苏州大学