Large Scaled Synthesis of Heterostructured Electrospun TiO2/SnO2 Nanofibers with an Enhanced Photocatalytic Activity

作者：Zhang, Li; Yu, Wei^*; Han, Cui; Guo, Jiang; Zhang, Qinghong; Xie, Hongyong; Shao, Qian^*; Sun, Zhiguo; Guo, Zhanhu^*

来源：Journal of the Electrochemical Society, 2017, 164(9): H651-H656.

DOI：10.1149/2.1531709jes

• VISIBLE-LIGHT PHOTOCATALYSIS
• TIO2 NANOPARTICLES
• ANATASE TIO2
• NANOCOMPOSITE
• DEGRADATION
• PHOTOLUMINESCENCE
• IRRADIATION
• EFFICIENT
• GRAPHENE
• DYE

Heterostructured TiO2/SnO2 fibrillar nanocomposites were synthesized by using electrospinning technology with the setup composed of a syringe pump with two parallel syringes on it and a rotating collector. The heterojunctions were formed between TiO2 and SnO2 nanofibers fast and efficiently on a large scale, after the fiberizing carrier polyvinylpyrrolidone (PVP) on the as-spun composite nanofibers was burnt away at 500 degrees C. The samples were characterized by scanning electron microscope (SEM), transmission electron microscopy (TEM), X-ray diffraction (XRD), X-ray photoelectron spectroscopy (XPS), UV-vis diffuse reflection spectroscopy (DRS), and photoluminescence spectra (PL), respectively. The results indicated that two kinds of small nanofibers with different diameters were interconnected to form heterojunctions. Photocatalytic tests displayed that the heterostructured TiO2/SnO2 nanofibers exhibited a much higher degradation rate of methylene blue (MB), rhodamine B (RhB), and 4-chlorophenol (4-CP) than that of bare TiO2 nanofibers or Evonik P25 under UV light irradiation. The enhanced photocatalytic activity could be attributed to the effective charge separation derived from the coupling effect of TiO2 and SnO2 nanocomposites.

• 出版日期2017
• 单位东华大学; 上海第二工业大学; 山东科技大学