Morphology characterization of polyaniline nano- and microstructures

作者：Hopkins Alan R^*; Lipeles Russell A; Hwang Son Jong

来源：Synthetic Metals, 2008, 158(14): 594-601.

DOI：10.1016/j.synthmet.2008.04.018

• polyaniline emeraldine base (PANI-EB)
• nanofibers
• microtubes
• solid-state nuclear magnetic resonance
• wide-angle X-ray scattering
• small-angle X-ray scattering

Small-angle neutron scattering (SANS), nuclear magnetic resonance (NMR), wide-angle and small-angle X-ray scattering (WAXS and SAXS) measurements were carried out to investigate the three morphological forms of polyaniline emeraldine base (PANI-EB): unstructured, microtubes, and nanofibers. Although the chemical backbone between these two materials is quite similar, their solid structures are quite different, showing differences in the molecular conformation and supramolecular packing. Detailed solid-state (13)C and (15)N NMR characterization of PANT nanofibers (compared to the unstructured, granular form) revealed a slight variation in the structural features of the polymer that led to some differences in the chemical environments of the respective nuclei. The presence of two extra-sharp peaks at 96.5 and 179.8 ppm is a distinct feature found exclusively in the nanofiber spectra. Moreover, the crosspolarization (CP) dynamics study disclosed the presence of a complete set of sharp NMR peaks that are responsible for the presence of a more ordered morphology in the nanofiber. Small-angle neutron scattering indicated very sharp interfaces in the PANT fibers, which are well organized and have extremely sharp domains within the length scales probed (similar to 10-1 nm). Overall, the X-ray scattering and spectroscopy data suggest that the nanofiber form is structurally different from the unstructured, PANI-EB powder. These differences are manifested, in part, by the additional chemistry occurring during the synthesis of the nanofibers. Published by Elsevier B.V.

• 出版日期2008-8