Aerobic oxidation of benzyl alcohol catalyzed by Cu-Mn mixed oxides and 2,2,6,6-tetramethyl-piperidyl-1-oxyl

作者：Guo Yanchun; Zhao Junfeng; Xu Jinxia; Wang Wei; Tian Fengshou; Yang Guanyu^*; Song Maoping

来源：Journal of Natural Gas Chemistry, 2007, 16(2): 210-212.

DOI：10.1016/S1003-9953(07)60050-4

• Cu-Mn oxides
• 2,2,6,6-tetrainethyl-piperidyl-1-oxyl aerobic oxidation
• benzyl alcohol

Heterogeneous Cu-Mn mixed oxides can mediate TEMPO-catalyzed selective oxidation of benzyl alcohol by molecular oxygen under neutral condition, and is recyclable. In the case of the molar ratio of Cu and Mn over 1, the highly-dispersed CuO inside the Cu-Mn mixed oxides is responsible for the good performances in catalytic oxidation.

• 出版日期2007-6
• 单位河南工程学院; 郑州大学