A Frequency-Response Study on Sorption of Thiophene and Benzene on NiY Zeolite

作者：Lai Junling^*; Song Lijuan; Sun Zhaolin

来源：China Petroleum Processing and Petrochemical Technology, 2011, 13(2): 24-28.

• frequency response
• thiophene
• benzene
• NiY zeolite
• adsorption site

The adsorption behavior of thiophene and benzene on NiY zeolite has been investigated by the frequency response (FR) method. The FR spectra of thiophene and benzene on NiY zeolite were recorded at 302-335 K in a pressure range of 26.6-266 Pa. The results showed that adsorption was found to be the rate-controlling process for the thiophene/NiY zeolite system, and there were two different adsorption processes. Two kinds of adsorption models have been proposed, namely: the S-M interaction (low frequency adsorption) and the pi-complexation (high frequency adsorption). High frequency adsorption obeyed the Langmuir model. By combining the FR method and Langmuir model, the adsorption site of high frequency adsorption process at 302 K and 335 K was 3.172 mmol/g and 2.974 mmol/g, respectively, and on the combined adsorption isotherms, the adsorption site of the low frequency adsorption process at 302 K and 335 K was 0.308 mmol/g and 0.436 mmol/g, respectively. The low frequency adsorption process (S-M interaction) was the main adsorption process. The diffusion process was the rate-controlling process for the benzene-NiY zeolite system.

• 出版日期2011-6
• 单位辽宁石油化工大学; 中国石油大学（华东）