New high-pressures vapor-liquid equilibrium data for the carbon dioxide+2-methyl-2-propanol binary system

作者：Sima Sergiu^*; Secuianu Catinca; Feroiu Viorel; Geana Dan

来源：CENTRAL EUROPEAN JOURNAL OF CHEMISTRY, 2014, 12(9): 893-900.

DOI：10.2478/s11532-013-0392-3

• Carbon dioxide
• 2-Methyl-2-Propanol (tert-butanol)
• SRK
• High-pressures
• EoS

New vapor-liquid equilibria (VLE) data at 323.15, 333.15, 343.15, and 353.15 K and pressures up to 112.9 bar are reported for the carbon dioxide + 2-methyl-2-propanol system. The experimental method used in this work was a static analytical method with liquid and vapor phases sampling using a rapid online sampler injector (ROLSI (TM)) coupled to a gas chromatograph (GC) for analysis. Measured VLE data and literature data for carbon dioxide + 2-methyl-2-propanol system were modeled with the Soave-Redlich-Kwong (SRK) cubic equation of state with classical van der Waals (two-parameter conventional mixing rule, 2PCMR) mixing rules. A single set of interaction parameters that lead to a correct phase behavior was used in this work to model the new VLE data and critical points of the mixtures in a wide range of temperature and pressure. The SRK prediction results were compared to the new data measured in this study and to available literature data.

• 出版日期2014-9