A New Acetate Selective Polyamine Receptor Based on Anthracene and 4-Nitrophenyl Group

作者：Lee Sung Kyu; Kang Jongmin^*

来源：BULLETIN OF THE KOREAN CHEMICAL SOCIETY, 2011, 32(4): 1228-1230.

DOI：10.5012/bkcs.2011.32.4.1228

• Anion receptor
• Polyamine receptor
• Hydrogen bond

A new amine receptor 2 utilizing anthracene and nitrophenyl group as signaling group was designed and synthesized. The receptor 2 only utilizes four amine N-H's and 9-anthracenyl hydrogen to bind anions. The receptor 2 can bind anions through hydrogen bonds with a selectivity of CH(3)CO(2)(-) > H(2)PO(4)(-) > F(-) > C(6)H(5)CO(2)(-) > Cl(-) in highly polar solvent such as DMSO without protonation of amine.

• 出版日期2011-4-20