A soft chemical route to multicomponent lithium transition metal oxide nanowires as promising cathode materials for lithium secondary batteries

作者：Park Dae Hoon; Lim Seung Tae; Hwang Seong Ju^*

来源：Electrochimica Acta, 2006, 52(4): 1462-1466.

DOI：10.1016/j.electacta.2006.02.044

• ID nanowires
• chemical oxidation
• solid-state precursor
• lithium nickel manganese oxide
• hexagonal layered structure
• electrode materials

We have synthesized 1D nanowires of lithium nickel manganese oxides with two different crystal structures through the chemical oxidation reaction of solid-state precursor LiMn0.5Ni0.5O2 under hydrothermal condition. According to X-ray diffraction and elemental analyses, the nanowires obtained by persulfate treatments at 65 and 120 degrees C crystallize with a hexagonal layered and an alpha-MnO2-type structure, respectively, in which nickel and manganese ions exist in octahedral sites. Electron microscopic analyses reveal that the platelike crystallites of the precursor are changed into nanowires with the diameter of similar to 20 run after the persulfate treatment. Thermal and infrared spectroscopic analyses clearly demonstrate that, in comparison with alpha-MnO2-structured nanowires, the hexagonal layered nanowires contain less water molecules in the lattice, which makes them suitable for the application as electrode materials for lithium secondary batteries. According to electrochemical measurements, the hexagonal layered nanowires show a larger discharge capacity and an excellent cyclability with respect to repeated Li intercalation-disintercalation process. X-ray diffraction and electron microscopic analyses on the samples subjected to electrochemical analysis reveal that the layered structure and I D morphology of the nanowires are still maintained after the electrochemical cyclings, which is responsible for their excellent electrochemical performances.

• 出版日期2006-12-1