A Strategy for the Synthesis of Anthraquinone-Based Aryl-C-glycosides

作者:Anand Namrata; Vpadhyaya Kapil; Ajay Arya; Mahar Rohit; Shukla Sanjeev K; Kumar Brijesh; Tripathi Rama Pati*
来源:Journal of Organic Chemistry, 2013, 78(10): 4685-4696.
DOI:10.1021/jo302589t

摘要

An efficient and simple strategy for the synthesis of a diverse range of anthraquinone-based aryl-C-glycosides has been developed. It involves the sequential Diels-Alder reaction and oxidative aromatization with the preformed glycosyl diene and dienophiles. The glycosyl dienes were obtained from simple sugars by tandem one-pot substitution and elimination reaction.

  • 出版日期2013-5-17