科研之友
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摘要
We propose a generic strategy for microsupercapacitor fabrication that integrates layers of reduced graphene oxide (rGO) and pseudocapacitive materials to create electrode heterostructures with significantly improved cycling stability and performance. Our approach involves a combination of photolithography and a simple transfer method of free-standing reduced graphene oxide film onto an Au/patterned photoresist bilayer. The resulting stack (rGO/Au/patterned resist/substrate) is then used for the electrochemical deposition of various pseudocapacitive materials before the final step of lift-off. To prove the viability of this method, we have successfully fabricated microsupercapacitors (MSCs) with the following interdigitated electrode heterostructures: MnO2/rGO, Co(OH)(2)/rGO and PANI/rGO. These MSCs show better performance and cycling stability compared to the single layer, (i.e., rGO-free) counterparts. The interdigitated electrode heterostructures result in MSCs with energy densities in the range of 3-12 mW h/cm(3) and power densities in the range of 400-1200 mW/cm(3), which is superior to the Li thin film batteries (E=10 mW h/cm(3)), carbon, and metal oxide based MSCs (E=1-6 mW h/cm(3)) while device energy densities are in the range of 1.3-5.3 mW h/cm(3), corresponding power densities are in the range of 178-533 mW/cm(3). These results can be explained by a facilitated nucleation model, where surface topology of the rGO film creates a favorable environment for the nucleation and growth of pseudocapacitive materials with strong interfacial contacts and enhanced surface area. This approach opens up a new avenue in fabricating MSCs involving a variety of heterostructures combining electrical double layer carbon type with Faradaic pseudocapacitive materials for enhanced electrochemical performance.
- 出版日期2015-9
