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摘要
A novel 3-D coordination polymer with trimeric copper (I) unit, [Cu-3(CN)(IN)(2)](n) (IN = isonicotinate), was hydrothermally synthesized by the reaction of Cu(NO3)(2).3H(2)O with isonicotinic and terephthalic acids. The structure was characterized to be a twofold interpenetrated 3-D coordination network polymer with two-coordinated copper(I). It has a powder SHG efficiency about that of KDP.
- 出版日期2004-5-7
- 单位结构化学国家重点实验室; 中国科学院福建物质结构研究所
