Nanoparticle Layer Deposition for Plasmonic Tuning of Microstructured Optical Fibers

作者：Csaki Andrea^*; Jahn Franka; Latka Ines; Henkel Thomas; Malsch Daniell; Schneider Thomas; Schroeder Kerstin; Schuster Kay; Schwuchow Anka; Spittel Ron; Zopf David; Fritzsche Wolfgang

来源：Small, 2010, 6(22): 2584-2589.

DOI：10.1002/smll.201001071

Plasmonic nanoparticles with spectral properties in the UV-to-near-IR range have a large potential for the development of innovative optical devices. Similarly, microstructured optical fibers (MOFs) represent a promising platform. technology for fully integrated, next-generation plasmonic devices; therefore, the combination of MOFs and plasmonic nanoparticles would open the way for novel applications, especially in sensing applications. In this Full Paper, a cost-effective, innovative nanoparticle layer deposition (NLD) technique is demonstrated for the preparation of well-defined plasmonic layers of selected particles inside the channels of MOFs. This dynamic chemical deposition method utilizes a combination of microfluidics and self-assembled monolayer (SAM) techniques, leading to a longitudinal homogeneous particle density as long as several meters. By using particles with predefined plasmonic properties, such as the resonance wavelength, fibers with particle-adequate spectral characteristics can be prepared. The application of such fibers for refractive-index sensing yields a sensitivity of about 78 nm per refractive index unit (RIU). These novel, plasmonically tuned optical fibers with freely selected, application-tailored optical properties present extensive possibilities for applications in localized surface plasmon resonance (LSPR) sensing.

• 出版日期2010-11-22