Diphenyldipyridinezinc(II): partial spontaneous resolution of an organometallic reagent

作者：Lennartson Anders^*; Hakansson Mikael

来源：Acta Crystallographica Section C-Crystal Structure Communications, 2009, 65(5): M205-M207.

DOI：10.1107/S0108270109014127

The title compound, [Zn(C(6)H(5))(2)(C(5)H(5)N)(2)], (I), forms conformationally chiral molecules residing on a twofold axis. The molecules are stacked along c, and these stacks are associated by edge-to-face pi-pi interactions. Crystals of (I) belong to the Sohncke space group P2(1)2(1)2 and the crystal lattice of (I) is chiral. The crystal batch that was examined consisted of a mixture of enantiomerically pure crystals and crystals twinned by inversion.

• 出版日期2009-5