Composition-dependent surface chemistry of colloidal BaxSr1-xTiO3 perovskite nanocrystals

作者:Margossian Tigran; Culver Sean P; Larmier Kim; Zhu Feng; Brutchey Richard L*; Coperet Christophe*
来源:Chemical Communications, 2016, 52(95): 13791-13794.
DOI:10.1039/c6cc07298d

摘要

BaxSr1-xTiO3 perovskite nanocrystals, prepared by the vapor diffusion sol-gelmethod and characterized by state of the art surface techniques, display significantly different O-H stretching frequencies and adsorption properties towards CO2 as a function of the alkaline earth composition (Ba vs. Sr). The difference of properties can be associated with the more basic nature of BaO-rich than SrO-rich surfaces.

  • 出版日期2016