A photoswitchable supramolecular complex with release-and-report capabilities

作者:Nilsson Jesper R; O'Sullivan Melanie C; Li S; Anderson Harry L; Andreasson Joakim*
来源:Chemical Communications, 2015, 51(5): 847-850.
DOI:10.1039/c4cc08513b

摘要

A self-assembled supramolecular platform has been designed for reversibly controlling the concentration of a compound in solution, via a photochemical reaction. The system utilizes metal-ligand interactions between a Zn-porphyrin dimer and a pyridine-appended dithienylethene (DTE) photoswitch. In addition to reversible compound release, the spectral properties of the release scaffold provide a fluorescence-based reporting function.

  • 出版日期2015