Multi-component reactions involving group 6 Fischer carbene complexes: a source of inspiration for future catalytic transformations

作者:Angel Fernandez Rodriguez Manuel; Garcia Garcia Patricia; Aguilar Enrique*
来源:Chemical communications, 2010, 46(41): 7670-7687.
DOI:10.1039/c0cc02337j

摘要

The ability of heteroatom stabilized Fischer carbene complexes (FCCs) to participate in multicomponent reactions (MCRs) has become a characteristic of such organometallics, particularly of chromium carbenes. This feature article updates the main results in this field during the last lustrum, highlighting the ability of FCCs for the construction of densely functionalized frameworks, mainly through the successive incorporation of unsaturated moieties (alkynes, CO ligands, ... ) in a sequential manner. Examples where up to seven components are coupled will be presented.

  • 出版日期2010