摘要
A new class of thermotropic lanthanidomesogens has been designed and prepared. They are based on 4-pyridone ligands that possess mesogenic cyanobiphenyl groups attached to the 4-pyridone unit via a flexible long alkyl spacer and show a very high thermal stability (decomposition temperatures near 300 degrees C). Depending on the alkyl length spacer, these complexes exhibit a SmA phase with transition temperatures influenced by the number of mesogenic groups employed and the spacer length.
- 出版日期2015