Bipolar Polymer Semiconductor Blends of C-60-End-Capped Poly(4-diphenylaminostyrene) and Poly(4-diphenylaminostyrene): One-Pot Synthesis and Charge-Transport Properties

作者：Natori Itaru^*; Natori Shizue; Sekikawa Hiroyuki; Takahashi Tomoyuki; Sato Hisaya

来源：Journal of Applied Polymer Science, 2011, 121(6): 3433-3438.

DOI：10.1002/app.33864

• anionic polymerization
• blends
• charge transport
• conducting polymers
• fullerenes

Three types of fullerene (C-60)-end-capped poly(4-diphenylaminostyrene) (C-60-PDAS) and poly(4-diphenylaminostyrene) (PDAS) blends were prepared to investigate their potential as bipolar polymer semiconductors. The concentration of C-60 in the C-60-PDAS/PDAS blends strongly affected the hole and electron drift mobility values; the hole drift mobility decreased with an increase in the C-60 concentration. However, the electron drift mobility increased with an increase in the C-60 concentration. The hole and electron drift mobility values were almost the same for the 1/2 C-60-PDAS/PDAS blend; therefore, this polymer blend was thought to be a bipolar polymer semiconductor.

• 出版日期2011-9-15