Microwave-Assisted Palladium(II)-Catalyzed Synthesis of Aryl Ketones from Aryl Sulfinates and Direct ESI-MS Studies Thereof

作者：Behrends Malte; Savmarker Jonas; Sjoberg Per J R; Larhed Mats^*

来源：ACS Catalysis, 2011, 1(11): 1455-1459.

DOI：10.1021/cs200428u

• palladium
• catalysis
• desulfination
• aryl sulfinates
• aryl ketones
• nitriles
• ESI-MS
• microwave

A fast palladium(II)-catalyzed and microwave-promoted procedure using 6-methyl-2,2'-bipyridyl as ligand to synthesize aryl ketones from aryl sulfinates and nitriles is described. More importantly, the first detailed investigation of the reaction mechanism using direct ESI-MS studies is reported.

• 出版日期2011-11