A new method of immobilizing ionic liquids into layered zirconium phosphates

作者：Wang Hai Yan; Han Da Xiong^*

来源：Chinese Chemical Letters, 2007, 18(6): 764-767.

DOI：10.1016/j.cclet.2007.04.021

• ionic liquids
• zirconium phosphates
• intercalation

In this work, a new method of a series of ion liquids (ILs) 1-alkyl-3-methylimidazolium chloride [C(n)mim]Cl (n = 2, 4, 6, 8) intercalation into layered zirconium phosphates was investigated. It was found that the alpha-ZrP center dot 2BA (i.e. pre-intercalated BA was arranged in a bilayer mode in the galleries of alpha-ZrP) was a suitable host for intercalation ILs: ILs was inserted through exchanging pre-intercalated BA. And the intercalation orientation was investigated by use of X-ray diffraction (XRD) experiments and molecular modeling calculation.

• 出版日期2007-6
• 单位国家海洋局第三海洋研究所; 厦门大学