Aqua-2 kappa O-mu-{N,N '-bis[2-(dimethylamino)ethyl]oxamidato(2-)}-1 kappa O-2,O ': 2 kappa N-4,N ',N '',N '''-bis(4,4 '-dimethyl-2,2 '-bipyridine-1 kappa N-2,N ')copper(II)nickel(II) bis (perchlorate) methanol hemisolvate

作者：Sun Wei; Li Yan Tuan^*; Wu Zhi Yong; Liu Jin Liang

来源：Acta Crystallographica Section C-Crystal Structure Communications, 2007, 63: M462-M464.

DOI：10.1107/S0108270107042643

In the crystal structure of the title complex, [ CuNi( C10H20N4O2)( C12H8N2)(2)( H2O)]( ClO4) 2 center dot 0.5CH(4)O or [ CuNi( dmaeoxd)( phen)(2)( H2O)]( ClO4)(2) center dot 0.5CH(3)OH {H(2)dmaeoxd is N, N'bis[ 2-( dimethylamino) ethyl] oxamide and phen is 1,10- phenanthroline}, the deprotonated dmaeoxd(2-). ligand is in a cis conformation and bridges the Cu-II and Ni-II atoms. The Cu-II atom is located in a slightly distorted square- based pyramidal environment, while the Ni-II atom is in an irregular octahedral environment. The binuclear Cu - Ni units interact with each other via pi-pi interactions, which results in an extended chain along the b axis.

• 出版日期2007-10
• 单位中国海洋大学