Asymmetric supercapacitors based on a NiCo2O4/three dimensional graphene composite and three dimensional graphene with high energy density

作者：Sun, Shumin; Wang, Shen; Li, Shaodan; Li, Yannan; Zhang, Yonghui; Chen, Junli; Zhang, Zhihong; Fang, Shaoming; Wang, Peiyuan^*

来源：Journal of Materials Chemistry A, 2016, 4(47): 18646-18653.

DOI：10.1039/c6ta07746c

• HIGH-PERFORMANCE SUPERCAPACITORS
• OXIDE RGO COMPOSITE
• ELECTROCHEMICAL PROPERTIES
• ELECTRODE MATERIALS
• NICKEL COBALTITE
• CYCLING STABILITY
• NANOSHEETS
• NANOWIRES
• STORAGE
• HYBRID

A NiCo2O4 nanoparticle/three dimensional porous graphene (NiCo2O4/3D-G) composite was synthesized through a facile hydrothermal method combined with subsequent annealing treatment. X-ray diffraction, X-ray photoelectron spectroscopy, and transmission electron microscopy analyses indicate that the NiCo2O4 nanoparticles were tightly anchored on the graphene sheets in the NiCo2O4/3D-G composite. When used as a supercapacitor electrode material, the obtained NiCo2O4/3D-G displayed a high specific capacitance of 2300 F g(-1) at 1.0 A g(-1) in 2.0 M KOH electrolyte. The asymmetric supercapacitor utilizing NiCo2O4/3D-G and 3D-G as positive and negative electrodes, respectively, delivered a high energy density of 73.8 W h kg(-1) with a power density of 800 W kg(-1) and tong cycle stability (94.3% capacitance retention after 5000 cycles). The excellent supercapacitive performance of the NiCo2O4/3D-G can be ascribed to the synergistic effect of the porous and conductive three-dimensional cross-linking 3D-G and the high pseudocapacitive performance of the NiCo2O4 nanoparticles.

• 出版日期2016-12-21
• 单位郑州轻工业大学