Hydrogen on nanocrystalline diamond film surfaces

作者:Zemek J*; Houdkova J; Jiricek P; Kozak H; Kromka A
来源:Diamond and Related Materials, 2012, 26: 66-70.
DOI:10.1016/j.diamond.2012.04.008

摘要

In this work we show the full quantification of surface composition of nanocrystalline diamond films (NCD), including hydrogen as a function of their surface morphology using X-ray-induced photoelectron spectroscopy and elastic peak electron spectroscopy. The surfaces of un-doped NCD films of various thickness deposited on Si/SiO2 substrates from methane and hydrogen gas mixture by microwave plasma chemical vapour deposition have been subjected to chemical treatment with H2SO4 + KNO3 at 200 degrees C to reduce a non-diamond phase and then hydrogenated in pure hydrogen plasma. To provide a comparison, the reference samples prepared under the same conditions but chemically untreated were analysed.

  • 出版日期2012-7