Analysis of residues of prometryne and acetochlor in soil-water system by solid-phase extraction and gas chromatography/mass spectrometry

作者：Tan Wei; Hu Xiaoxu; Yang Min; Barrow Colin J; Yang Wenrong^*; Wang Hongbin

来源：Desalination and Water Treatment, 2014, 52(4-6): 1177-1182.

DOI：10.1080/19443994.2013.827310

• Soil
• Prometryne
• Acetochlor
• Solid-phase extraction
• Gas chromatography-mass spectrometer

A highly sensitive and simple analytical method was developed for analyzing the binary mixed pesticides of prometryne and acetochlor in soil-water system by gas chromatography/mass spectrometry (GC/MS). The sample solution was first purified by C-18 solid-phase extraction column, which was leached by acetone. The leachate was enriched to 1.0mL by pressure blowing concentrator and then analyzed by GC/MS. The linear calibration curves were showed in the range of 1-15g/mL with a correlation coefficient of 0.9991. The average recoveries (n=5) were between 95.3 and 115.7%, with relative standard deviations ranged from 1.71 and 7.95%. The limits of detection of Prometryne/Acetochlor were up to 0.06 and 0.17g/mL, respectively. This method provides a reliable approach to examine and evaluate the residues of prometryne and acetochlor in the soil-water system.

• 出版日期2014-1-28
• 单位云南民族大学