An in-Ketocyclophane

作者:Qin Qian; Mague Joel T; Pascal Robert A Jr*
来源:Organic Letters, 2010, 12(5): 928-930.
DOI:10.1021/ol9028572

摘要

Computational studies indicate that some benzophenone-capped cyclophanes should have carbonyl groups pointed directly at their basal benzene rings as a result of conformational restraints imposed by bulky groups in the linking arms of the molecules. Cyclophane 4 was prepared, and its X-ray structure shows it to be the first in-ketocyclophane.

  • 出版日期2010-3-5