Determination of Trace Chloroanilines in Environmental Water Samples Using Hollow Fiber-Based Liquid Phase Microextraction

作者：Young Anna; Lai Guida; Hung Brian; Yuen Amy; He Yi^*

来源：Chromatographia, 2011, 74(1-2): 83-88.

DOI：10.1007/s10337-011-2022-6

• Hollow fiber-based liquid phase microextraction
• Chloroanilines
• River water

A liquid phase microextraction method using hollow fiber to support extraction solvent was developed for enrichment of trace level chloroanilines in environmental water samples. Target analytes, 2-chloroaniline, 3-chloroaniline, 2,3-dichloroaniline, 2,4-dichloroaniline, 3,4-dichloroaniline, and 3,5-dichloroaniline were determined using gas chromatography-flame ionization detector after extraction. Experimental conditions that affect extraction efficiency were investigated and optimized. The proposed method showed a wide linear range from lower mu g L(-1) to 1,000 mu g L(-1), low detection limits (a parts per thousand currency sign5.1 mu g L(-1)), and reasonable relative standard deviations (RSDs < 13%). Feasibility of the method was evaluated by analyzing river water samples collected from the Hudson River and the East River in New York City.

• 出版日期2011-7