Nd-Co substituted strontium hexaferrite powders with enhanced coercivity

作者：Herme C A; Bercoff P G^*; Jacobo S E

来源：Materials Research Bulletin, 2012, 47(11): 3881-3887.

DOI：10.1016/j.materresbull.2012.08.047

• Magnetic materials
• Sol-gel chemistry
• X-ray diffraction
• Magnetic properties
• Magnetic structure

In this work we report the synthesis of Nd-Co substituted strontium hexaferrites of composition Sr1-xNdxFe11-xCoxO19 by the sol-gel auto-combustion method with further heat treatment. The analysis of the X-ray diffraction spectra shows the M-type hexagonal structure in samples treated at 1100 degrees C for 2 h. Coercivity increases 11% with 0.2 Nd-Co substitution, reaching a value of 68.9 A/m (5480 Oe) while saturation magnetization is reduced 6% to 91 A m(2)/kg (91 emu/g). The behavior of magnetic susceptibility with an applied field shows two different maxima which are assigned to different magnetic orderings. This assumption is supported by the appearance of two experimental values of Curie temperatures (T-C) for all the prepared samples. Magnetic susceptibility chi and T-C measurements suggest an uneven distribution of the iron vacancies.

• 出版日期2012-11