An unprecedented oxidative intermolecular homo coupling reaction between two sp(3)C-sp(3)C centers under metal-free condition

作者：Sahoo Santosh K^*

来源：Tetrahedron Letters, 2016, 57(31): 3476-3480.

DOI：10.1016/j.tetlet.2016.06.092

• Metal free
• C-C coupling
• Dibenzylic
• Alkanes
• CDC reaction

An unprecedented formation of benzylic sp(3)C-sp(3)C coupled dibenzylic products has been illustrated. The reactions have been carried out in the presence of three oxidizing reagents, i.e., diacetoxy-iodobenzene (IBDA), N-fluorobenzenesulfonimide (NFSI), and pyridine (Py) using toluene derivatives.

• 出版日期2016-8-3