A simple naphthalene-based colorimetric sensor selective for acetate

作者:Goswami Shyamaprosad*; Das Avijit Kumar; Sen Debabrata; Aich Krishnendu; Fun Hoong Kun; Quah Ching Kheng
来源:Tetrahedron Letters, 2012, 53(36): 4819-4823.
DOI:10.1016/j.tetlet.2012.06.104

摘要

A new naphthalene based receptor (L) has been designed and synthesized which shows a remarkable color change from colorless to pink on selective binding with acetate. The anion recognition property of the receptor via hydrogen bonding interactions is monitored by UV-vis, fluorescence, and H-1 NMR titrations. It is observed that in each case, the receptor shows a specific selectivity toward the acetate ion over other interfering anions. Thus, a significant bathochromic shift in UV-vis spectrum with a sharp pink color in %26apos;naked-eye%26apos; makes the receptor suitable for the detection of the acetate ion.

  • 出版日期2012-9-5