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摘要
A new microporous metal - organic framework compound featuring chiral ( salen) Mn struts is highly effective as an asymmetric catalyst for olefin epoxidation, yielding enantiomeric excesses that rival those of the free molecular analogue. Framework confinement of the manganese salen entity enhances catalyst stability, imparts substrate size selectivity, and permits catalyst separation and reuse.
- 出版日期2006
- 单位西北大学
