A novel molten-salt electrochemical cell for investigatingthe reduction of uranium dioxide to uranium metal by lithium using in situ synchrotron radiation

作者：Brown Leon D; Abdulaziz Rema; Jervis Rhodri; Bharath Vidal; Mason Thomas J; Atwood Robert C; Reinhard Christina; Connor Leigh D; Inman Douglas; Brett Daniel J L; Shearing Paul R^*

来源：JOURNAL OF SYNCHROTRON RADIATION, 2017, 24(2): 439-444.

DOI：10.1107/S1600577517000625

• cell design
• molten-salt reduction
• spent fuel reprocessing
• energy-dispersive X-ray diffraction

A novel electrochemical cell has been designed and built to allow for in situ energy-dispersive X-ray diffraction measurements to be made during reduction of UO2 to U metal in LiCl-KCl at 500 degrees C. The electrochemical cell contains a recessed well at the bottom of the cell into which the working electrode sits, reducing the beam path for the X-rays through the molten-salt and maximizing the signal-to-noise ratio from the sample. Lithium metal was electrodeposited onto the UO2 working electrode by exposing the working electrode to more negative potentials than the Li deposition potential of the LiCl-KCl eutectic electrolyte. The Li metal acts as a reducing agent for the chemical reduction of UO2 to U, which appears to proceed to completion. All phases were fitted using Le Bail refinement. The cell is expected to be widely applicable to many studies involving molten-salt systems.

• 出版日期2017-3