Using a beta-Cyclodextrin-functional Fe3O4 as a Reinforcement of PLA: Synthesis, Thermal, and Combustion Properties

作者：Ansari Hossein; Shabanian Meisam^*; Khonakdar Hossein Ali

来源：Polymer - Plastics Technology and Engineering, 2017, 56(12): 1366-1373.

DOI：10.1080/03602559.2016.1275687

• Functional Fe3O4
• nanocomposite
• polylactic acid
• thermal properties

In this work, Fe3O4 nanoparticles were chemically grafted with -cyclodextrin (-CD@Fe3O4). Fe3O4 nanoparticles were modified using N,N-dimethylformamide as a solvent, -cyclodextrin as a modifier, and 3-glycidoxypropyltrimethoxysilane as a coupling agent at room temperature. The obtained modified Fe3O4 were characterized by X-ray diffraction, Fourier transform infrared spectroscopy, field emission scanning electron microscopy, transmission electron microscopy, and thermogravimetric analysis techniques. -CD@Fe3O4 was incorporated into a poly(lactic acid) matrix to prepare new green nanocomposites with modified properties. -CD@Fe3O4 showed good dispersion in the poly(lactic acid) matrix and thermal and combustion properties of the nanocomposites were improved.
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• 出版日期2017