Decomposition of a mixed-valence [2Fe-2S] cluster gives linear tetra-ferric and ferrous clusters

作者：Saouma Caroline T; Kaminsky Werner; Mayer James M^*

来源：Polyhedron, 2013, 58: 60-64.

DOI：10.1016/j.poly.2012.07.057

• Iron sulfur clusters

Despite the ease of preparing di-ferric [2Fe-2S] clusters, preparing stable mixed-valence analogues remains a challenge, as these clusters have limited thermal stability. Herein we identify two decomposition products of the mixed-valence thiosalicylate-ligated [2Fe-2S] cluster, [Fe2S2(SArCOO)(2)](3-)((SArCOO)(2-) = thiosalicylate).

• 出版日期2013-7-13