科研之友
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摘要
Chemomechanical effects are known to initiate fluid oscillations in certain liquid metals; however, they typically produce an irregular motion that is difficult to deactivate or control. Here we show that stimulating liquid gallium with electrochemistry can cause a metal drop to exhibit a heart beating effect by shape shifting at a telltale frequency. Unlike the effects reported in the past for mercury, the symmetry-breaking forces generated by using gallium propel the drop several millimeters with velocities of the order of 1 cm per second. We demonstrate pulsating dynamics between 0 and 610 beats per minute for 50-150 mu L droplets in a NaOH electrolyte at 34 degrees C. The underlying mechanism is a self-regulating cycle initiated by fast electrochemical oxidation that adjusts the drop's surface tension and causes a transformation from spherical to pancake form, followed by detachment from the circular electrode. As the beat frequency can be activated and controlled using a dc voltage, the electrochemical mechanism opens the way for fluid-based timers and actuators.
- 出版日期2018-7-11
- 单位中国科学院理化技术研究所
