An efficient and recyclable ionic diphosphine-based Ir-catalyst for hydroaminomethylation of olefins with H2O as the hydrogen source

作者：Liu, Huan; Yang, Da; Wang, Dong-Liang; Wang, Peng; Lu, Yong; Vo-Thanh Giang; Liu, Ye^*

来源：Chemical communications, 2018, 54(57): 7979-7982.

DOI：10.1039/c8cc03431a

• TRANSITION-METAL CATALYSIS
• GAS SHIFT REACTION
• AMINES
• HYDROFORMYLATION
• HYDROAMINATION
• VINYLARENES
• ALKYLATION
• 1-OCTENE

Hydroaminomethylation of olefins with H2O as the hydrogen source was accomplished over an Ir-catalyst with the involvement of an ionic diphosphine (L6). The use of H2O as the hydrogen source could completely inhibit the hydrogenation of olefins. The -accepting ability and improved stability of L6 endowed the corresponding Ir-catalyst with high activity and good longevity for recycling uses.

• 出版日期2018-7-21
• 单位华东师范大学