A novel N-alkylation of amines by alkyl halides on mixed oxides at room temperature

作者：Gawande Manoj B; Deshpande Sameer S; Satam Jitendra R; Jayaram Radha V^*

来源：Catalysis Communications, 2007, 8(3): 576-582.

DOI：10.1016/j.catcom.2006.08.011

• N-alkylation
• mixed oxides
• tertiary amines
• liquid phase reaction
• room temperature (30 degrees C)

Selective liquid phase N-alkylation of amines by alkyl halides using Al2O3-OK as a catalyst in the presence of acetonitrile at room temperature (30 degrees C) is described. The Al2O3-OK catalyst was characterized by XRD, SEM-EDXS, elemental analysis, particle size analysis, BET surface area, pore size and average pore diameter. The catalyst used for this synthetically useful transformation showed a considerable level of reusability as well as good activity.

• 出版日期2007-3