A Hemimethyl-Substituted Cucurbit[7]uril Derived from 3 alpha-Methyl-glycoluril

作者:Zhao, Wen-Xuan; Wang, Chuan-Zeng; Chen, Li-Xia; Cong, Hang; Xiao, Xin; Zhang, Yun-Qian; Xue, Sai-Feng; Huang, Ying; Tao, Zhu*; Zhu, Qian-Jiang
来源:Organic Letters, 2015, 17(20): 5072-5075.
DOI:10.1021/acs.orglett.5b02588

摘要

A novel hemimethyl-substituted cucurbit[7]uril (HMeQ[7]) derived from 3 alpha-methyl-glycoluril has been prepared. HMeQ[7] is readily soluble in both water and dimethyl sulfoxide (DMSO) and displays not only host guest interaction properties similar to those of the normal cucurbit[7]uril but also unusual properties in DMSO.