mu(2)-Alkyne dicobalt(0)hexacarbonyl complexes as carbon monoxide-releasing molecules (CO-RMs): probing the release mechanism

作者：Atkin Anthony J; Williams Sophie; Sawle Philip; Motterlini Roberto; Lynam Jason M; Fairlamb Ian J S^*

来源：Dalton Transactions, 2009, (19): 3653-3656.

DOI：10.1039/b904627p

The first carbon monoxide-releasing molecules (CO-RMs) based on mu(2)-alkyne dicobalt(0)hexacarbonyl complexes are reported. The alkyne substituents significantly affect the rate of CO-release, cytotoxicity and cell viability. Mechanistic studies provide insight into the CO-RM activation pathways.

• 出版日期2009
• 单位河北医科大学