A synthesis of crystalline Li7P3S11 solid electrolyte from 1,2-dimethoxyethane solvent

作者：Ito Seitaro^*; Nakakita Moeka; Aihara Yuichi; Uehara Takahiro; Machida Nobuya

来源：Journal of Power Sources, 2014, 271: 342-345.

DOI：10.1016/j.jpowsour.2014.08.024

• Sulfide
• Ion conductor
• Liquid phase synthesis
• Solid electrolyte
• Solid state battery

A crystalline solid electrolyte, Li7P3S11, was synthesized by a liquid-phase reaction of Li2S and P2S5 in an organic solvent. A precursor, which was a mixture of solvated Li3PS4 and Li4P2S7, was prepared by mixing Li2S and P2S5 powders in 1,2-dimethoxyethane (DME) solvent. After a vacuum drying of the precursor, the crystalline phase of Li7P3S11 was obtained by heat treatment at 250 degrees C for I h in Ar atmosphere. The Li7P3S11 sample showed high ionic conductivity of 2.7 x 10(-4) S cm(-1) at room temperature. The liquid-phase synthesis of the solid electrolyte has advantages for mass-production of all-solid-state batteries.

• 出版日期2014-12-20